It was two decades ago when Kei Hirose – a geochemist expert in high-pressure, deep-Earth phenomena – began researching a long-standing problem in understanding the working of the lower depths of our planet’s enormous mantle: the last 300 kilometers before the boundary with the scalding iron core.
Much of the mantle – which makes up 60 percent of the volume of the Earth – consists of the mineral recently named bridgmanite (MgSiO3), which is ordered in a particular crystal structure.
This had been well established for some decades, but there was an anomaly that kept on appearing when seismologists examined the mantle’s lower depths or “D” layer, some 2,600 to 2,900 kms from the surface. But since bridgmanite in its high-pressure “perovskite” crystal structure was considered to be one of the most stable materials on Earth, many were content to explain the anomaly as being of limited importance.
Hirose – also the director of the Earth-Life Science Institute (ELSI) since 2012 – instead theorized that the bottom layer contained materials similar to bridgmanite, but with crystal structures changed by the high pressures. And in 2002, he and his lab showed that when the material that is bridgmanite was under enormous pressure, it experienced a phase change into a modified substance. It was given the name post-perovskite because it had a crystal structure that was related to perovskite structure, but was also significantly different.
This discovery led to numerous other advances in understanding how heat from the core is transferred into the mantle and ultimately to the surface, and also how the presence of different deep subsurface materials and conditions result in surface changes, such as in the rate of volcanic activity in a region.
The Suizhou meteorite fell in 1986 and most of its parts are kept in the Academy of Sciences in China. But some samples have been released to outside museums and institutions, and the study of one has resulted in the discovery of the new mineral hiroseite. (Meteorites Australia)
Skip forward now to the summer of 2019. Italian meteorite analyst Luca Bindi of the University of Florence was studying a meteor that had fallen in 1986 and had been collected outside the Chinese city of Suizhou, in Hubei province in the middle of the country.
Among the tests that Bindi performed over a four year period was one to see what very high-pressure minerals might have been formed along the veins of the meteorite. The shock experienced by meteorites, generally when they collide in deep space, can change the composition and crystal structures of component minerals just as they change under pressure in the deep Earth.
Bindi had already made a number of other discoveries from his sample of the Suizhou meteorite and then he found – rather by accident – the mineral FeSiO3, formed with the distinctive perovskite crystal structure.
Bindi knew of the theorized existence of such a mineral – a super-high-pressure iron-rich form of bridgmanite – and understood that it had never been identified in nature before.
What’s more, he said, the physical alterations that form hiroseite provide unique direct evidence of a process some think is responsible for establishing the oxidation state of the Earth’s mantle, and the original formation of the metallic core. So, it could be quite a significant mineral.
A small hiroseite crystal handpicked from a section of the Suizhou meteorite and used for the X-ray single-crystal diffraction study, which allowed for an understanding of the structural details. The black rod is a carbon fiber (5 microns in diameter), which, in turn, is attached to a glass rod (not visible in the image). (Luca Bindi)
Hirose and other researchers with him use diamond anvil cell devices and lasers to conduct experiments in order to reproduce the very high pressures and temperatures that act on minerals deep in the Earth.
It turned out that Hirose had also been studying the material that Bindi identified and had been trying to synthesize in his lab, but without success. That, however, is not why Bindi selected hiroseite as the name of the mineral.
As Bindi wrote in an email, “when you discover a mineral which could be so important for the interior of our planet, you have to think seriously about the name you want to assign it. After careful thinking, I decided on ‘hiroseite,’ to honor Kei Hirose, a specialist of perovskite-post-perovskite phases.”
In an upcoming paper, he further wrote that he selected Hirose “for his fundamental contributions to the discovery of the post-perovskite phase in particular, and to the mineralogy of mantle perovskite in general.”
Hirose received an email from Bindi in July informing him that he was going to propose the name hiroseite for the mineral when it went for approval before the International Mineralogical Association. And in August, the iron-rich bridgmanite mineral with the perovskite crystal structure was indeed approved by the association and given a name that would acknowledge the work of Kei Hirose.
Bridgmanite is the high-pressure mineral found in the large section of the mantle shown here in orange, making up some 60 percent of the Earth’s matter by volume. It is always in what is called a perovskite crystal structure. The post-perovskite mineral phase, with its transformed and flatter crystal structure, was described and pioneered by Hirose and resides in the lower portion of the mantle. Hiroseite is found largely in the deep mantle as well.
There is a tradition in mineralogy of naming minerals after important scientists in the field. The name bridgmanite, for instance, was given in 2014 and is an appreciation of the work of American physicist Percy Williams Bridgman, who won the Nobel Prize in 1946 for his work in the physics of high pressure.
Because minerals formed under high pressure and high temperatures deep in the Earth’s mantle are not stable on the surface, they cannot be found there. This means mineralogists such as Bindi regularly look to meteorites to find new varieties of high-pressure minerals. The meteorites experience shock and very high temperatures when they collide with each other in deep space, and those conditions can form the high-pressure minerals otherwise present only in the deep subsurface on Earth.
Indeed, the only way to formally identify a high-pressure mineral is from a meteorite. This is because for a mineral to be named, a specimen of it must first be found in nature. And while minerals such as bridgmanite and now hiroseite make up a substantial part of the Earth, they are only stable thousands of kilometers beneath the planet’s surface and, at times, in the veins of meteorites.
The most abundant mineral on Earth, bridgmanite, was named in 2014 after Percy W. Bridgman, recipient of the 1946 Nobel Prize in Physics. (Public domain)
While bridgmanite is the most common mineral on Earth (by far), hiroseite is significantly less widespread below the Earth’s surface. Nonetheless, Hirose estimated that about 4 percent of the Earth’s matter by volume is hiroseite. This includes both the mineral itself and the mineral as it exists as an iron-rich component of bridgmanite.
There are about 3,800 named minerals on Earth, and some 40 to 50 new ones are formally accepted and named each year. The mineral ‘maruyamaite’, for instance, was named after ELSI Principal Investigator Shigenori Maruyama in 2013.
A major distinction between bridgmanite and hiroseite is that the latter has much more iron, while the former has more magnesium.
Because of the physical properties of iron, hiroseite is significantly different from bridgmanite, Hirose said. Hiroseite can introduce more electrical currents and conductivity into the mantle, and the color and density of the mantle will depend on how much iron is present in the minerals.
And because iron is a heavy element, the hiroseite with increased iron will be found in the lower depths of the mantle, even in the boundary area that touches the liquid portion of the iron core.
For bridgmanite, the peak shock conditions needed to create the mineral in its crystal form are greater than 24 gigapascals (considerably more pressure than that needed to form a diamond) and more than 1,427 degrees Celsius/2,600 degrees Fahrenheit. 2,600 degrees Fahrenheit.
Remarkably, the peak shock conditions for hiroseite are 60 gigapascals, dramatically more external pressure than that needed to form bridgmanite.
Director Kei Hirose at the Earth-Life Science Institute. (Nerissa Escanlar)
“Finding this mineral in the meteorite is very welcome and more results could come from it,” Hirose said. “We now have a mineral that we had identified computationally but not in a lab.”
While a variant of hiroseite with magnesium – (Mg,Fe)SiO3 hiroseite – has been synthesized above 60 gigapascals, hiroseite with FeSiO3 end-member composition is not stable thermodynamically and has never been synthesized in a lab.
Hirose, who has won numerous awards, including the Japan Academy Prize, said it was a “special honor” to have the mineral, or mineral component, named after him. And it was a special honor in part because, he said, it is probably the last high-pressure, deep-Earth mineral that will be named.
That’s because the basic mineral components of the mantle have now been named. What remains unnamed is the minerals with a post-perovskite crystal structure, the ones in the last 300 kilometers of the lower mantle.
They will never get named because they cannot exist anywhere except deep in the mantle, Hirose said. So, after hiroseite, the naming of high-pressure mantle minerals is over.
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Marc Kaufman has written books on astrobiology and Mars, has been a longtime reporter at The Washington Post and The Philadelphia Inquirer, and writes the NASA-supported online column Many Worlds (www.manyworlds.space) He has also had the good fortune to visit and work at ELSI numerous times and he wrote "ELSI RISING" -- the story of ELSI's origins and evolution -- in 2017.